Complementary angles add up to 90∘
When two angles' measures add up to 90∘, the angles are called complementary (to each other). Since angles have to measure less than 90∘ to add up to a right angle, only acute angles can be complementary to each other.
In the image above, angles ABC and DEF are complementary. We can tell because they're congruent with angles GHJ and JHI (respectively), and we can tell from the picture that GHJ and JHI add up to make GHI... which is a right angle.